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Case Western Reserve University

High-Power Titanate Capacitor for Power Electronics

There is a constant demand for better performing, more compact, lighter-weight, and lower-cost electronic devices. Unfortunately, the materials traditionally used to make components for electronic devices have reached their limits. Case Western Reserve University is developing capacitors made of new materials that could be used to produce the next generation of compact and efficient high-powered consumer electronics and electronic vehicles. A capacitor is an important component of an electronic device. It stores an electric charge and then discharges it into an electrical circuit in the device. Case Western is creating its capacitors from titanium, an abundant material extracted from ore which can be found in the U.S. Case Western's capacitors store electric charges on the surfaces of films, which are grown on a titanium alloy electrode that is formed as a spinal column with attached branches. The new material and spine design make the capacitor smaller and lighter than traditional capacitors, and they enable the component to store 300% more energy than capacitors of the same weight made of tantalum, the current industry standard. Case Western's titanium-alloy capacitors also spontaneously self-repair, which prolongs their life.

CUNY Energy Institute

Low-Cost Grid-Scale Electrical Storage Using a Flow-Assisted Rechargeable Zinc-Manganese Dioxide Battery

City University of New York (CUNY) Energy Institute is working to tame dendrite formation and to enhance the lifetime of Manganese in order to create a long-lasting, fully rechargeable battery for grid-scale energy storage. Traditional consumer-grade disposable batteries are made of Zinc and Manganese, two inexpensive, abundant, and non-toxic metals, but these disposable batteries can only be used once. If they are recharged, the Zinc in the battery develops filaments called dendrites that grow haphazardly and disrupt battery performance, while the Manganese quickly loses its ability to store energy. CUNY Energy Institute is also working to reduce dendrite formation by pumping fluid through the battery, enabling researchers to fix the dendrites as they form. The team has already tested its Zinc battery through 3,000 recharge cycles (and counting). CUNY Energy Institute aims to demonstrate a better cycle life than lithium-ion batteries, which can be up to 20 times more expensive than Zinc-based batteries.

CUNY Energy Institute


City University of New York (CUNY) Energy Institute is developing less expensive, more efficient, smaller, and longer-lasting power converters for energy-efficient LED lights. LEDs produce light more efficiently than incandescent lights and last significantly longer than compact fluorescent bulbs, but they require more sophisticated power converter technology, which increases their cost. LEDs need more sophisticated converters because they require a different type of power (low-voltage direct current, or DC) than what's generally supplied by power outlets. CUNY Energy Institute is developing sophisticated power converters for LEDs that contain capacitors made from new, nanoscale materials. Capacitors are electrical components that are used to store energy. CUNY Energy Institute's unique capacitors are configured with advanced power circuits to more efficiently control and convert power to the LED lighting source. They also eliminate the need for large magnetic components, instead relying on networks of capacitors that can be easily printed on plastic substrate. CUNY Energy Institute's prototype LED power converter already meets DOE's 2020 projections for the energy efficiency of LED power converters.

Det Norske Veritas (U.S.A)

Third Party Valuation of Grid and Microgrid Energy Storage Technologies

Det Norske Veritas (DNV GL) and Group NIRE will provide a unique combination of third-party testing facilities, testing and analysis methodologies, and expert oversight to the evaluation of ARPA-E-funded energy storage systems. The project will leverage DNV GL's deep expertise in economic analysis of energy storage technologies, and will implement economically optimized duty cycles into the testing and validation protocol. DNV GL plans to test ARPA-E storage technologies at its state-of-the-art battery testing facility in partnership with the New York Battery and Energy Storage Technology Consortium. Those batteries that pass the rigorous evaluation process will be adapted for testing under real world conditions on Group NIRE's multi-megawatt, wind-integrated microgrid in Texas. Testing will show how well the ARPA-E storage technologies can serve critical applications and will assist ARPA-E-funded battery developers in identifying any issues with performance and durability. This testing will also deliver performance data that buyers of grid storage need, enabling informed choices about commercial adoption of grid storage technologies.

Dioxide Materials, Inc.

High Efficiency Alkaline Water Electrolyzers for Grid Scale Energy Storage

The team led by Dioxide Materials will develop an alkaline water electrolyzer for an improved power-to-gas system. The team's electrochemical cells are composed of an anode, a cathode, and a membrane that allows anions to pass through, while being electrically insulating. High-conductivity anion exchange membranes are rare and often do not have the chemical or mechanical stability to withstand H2 production at elevated pressures. Therefore, the project is focused on developing an anion exchange membrane that is low-cost, is manufacturable in a scaleable process, and has sufficient conductivity, chemical stability, and mechanical strength. Moreover, by operating at alkaline instead of acidic conditions, the electrochemical cells do not need to use expensive precious metal catalysts, which most systems require to prevent corrosion. Dioxide Materials estimates that operating under alkaline conditions could lead to a 10x lower electrolyzer stack cost due to higher current densities and lower material costs (i.e. non-precious metals). The system will be compatible with intermittent energy sources because it can operate at lower temperatures than competiting technologies, thus allowing startup times on the order of seconds.


Planar Na-beta Batteries for Renewable Integration and Grid Applications

EaglePicher Technologies is developing a sodium-beta alumina (Na-Beta) battery for grid-scale energy storage. High-temperature Na-Beta batteries are a promising grid-scale energy storage technology, but existing approaches are expensive and unreliable. EaglePicher has modified the shape of the traditional, tubular-shaped Na-Beta battery. It is using an inexpensive stacked design to improve performance at lower temperatures, leading to a less expensive overall storage technology. The new design greatly simplifies the manufacturing process for beta alumina membranes (a key enabling technology), providing a subsequent pathway to the production of scalable, modular batteries at half the cost of the existing tubular designs.

Echogen Power Systems (DE), Inc.

Low-cost, long duration electrical energy storage using a CO2-based Pumped Thermal Energy Storage (PTES) system

The Echogen Power Systems team will develop an energy storage system that uses a carbon dioxide (CO2) heat pump cycle to convert electrical energy into thermal energy by heating a "reservoir" of low-cost materials such as sand or concrete. During the charging cycle, the reservoir will store the heat that will be converted into electricity on demand in the discharge or generating cycle. To generate power, liquid CO2 will be pumped to a supercritical pressure and brought to a higher temperature using the stored heat from the reservoir. Finally, the supercritical CO2 will be used to expand through a turbine to generate electricity during the discharge cycle.

Energy Storage Systems, Inc.

25kW 200kWh Energy Storage System based on All-iron Hybrid Flow Battery

Energy Storage Systems (ESS) is developing a cost-effective, reliable, and environmentally friendly all-iron hybrid flow battery. A flow battery is an easily rechargeable system that stores its electrolyte--the material that provides energy--as liquid in external tanks. Currently, flow batteries account for less than 1% of the grid-scale energy storage market because of their high system costs. The ESS flow battery technology is distinguished by its cost-effective electrolytes, based on earth-abundant iron, and its innovative battery hardware design that dramatically increases power density and enables a smaller and less costly battery. Creating a high-performing and low-cost storage system would enable broad adoption of distributed energy storage systems and help bring more renewable energy technologies--such as wind and solar--onto the grid.

Fluidic, Inc.

Enhanced Metal-Air Energy Storage System with Advanced Grid-Interoperable Power Electronics Enabling Scalability and Ultra-Low Cost

Fluidic Energy is developing a low-cost, rechargeable, high-power module for Zinc-air batteries that will be used to store renewable energy. Zinc-air batteries are traditionally found in small, non-rechargeable devices like hearing aids because they are well-suited to delivering low levels of power for long periods of time. Historically, Zinc-air batteries have not been as useful for applications which require periodic bursts of power, like on the electrical grid. Fluidic hopes to fill this need by combining the high energy, low cost, and long run-time of a Zinc-air battery with new chemistry providing high power, high efficiency, and fast response. The battery module could allow large grid-storage batteries to provide much more power on very short demand--the most costly kind of power for utilities--and with much more versatile performance.

Form Energy, Inc.


Form Energy will develop a long-duration energy storage system that takes advantage of the low cost and high abundance of sulfur in a water-based solution. Previous MIT research demonstrated that aqueous sulfur flow batteries represent the lowest chemical cost among rechargeable batteries. However, these systems have relatively low efficiency. Conversely, numerous rechargeable battery chemistries with higher efficiency have high chemical costs. The solution requires low chemical cost, high efficiency, and streamlined architecture. The team will pursue several competing strategies and ultimately select a single approach to develop a prototype system. Focus areas include developing anode and cathode formulations, membranes, and physical system designs.

General Atomics

GRIDS Soluble Lead Flow Battery Technology

General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low-cost materials. The goal is to develop a system that is far more durable than today's lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

General Compression

Fuel-Free, Ubiquitous, Compressed Air Energy Storage and Power Conditioning

General Compression has developed a transformative, near-isothermal compressed air energy storage system (GCAES) that prevents air from heating up during compression and cooling down during expansion. When integrated with renewable generation, such as a wind farm, intermittent energy can be stored in compressed air in salt caverns or pressurized tanks. When electricity is needed, the process is reversed and the compressed air is expanded to produce electricity. Unlike conventional compressed air energy storage (CAES) projects, no gas is burned to convert the stored high-pressure air back into electricity. The result of this breakthrough is an ultra-efficient, fully shapeable, 100% renewable and carbon-free power product. The GCAES system can provide high quality electricity and ancillary services by effectively integrating renewables onto the grid at a cost that is competitive with gas, coal, and nuclear generation.

Halotechnics, Inc.

Advanced Molten Glass for Heat Transfer and Thermal Energy Storage

Halotechnics is developing a high-temperature thermal energy storage system using a new thermal-storage and heat-transfer material: earth-abundant and low-melting-point molten glass. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night--when the sun is not out--to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. Halotechnics new thermal storage material targets a price that is potentially cheaper than the molten salt used in most commercial solar thermal storage systems today. It is also extremely stable at temperatures up to 1200°C--hundreds of degrees hotter than the highest temperature molten salt can handle. Being able to function at high temperatures will significantly increase the efficiency of turning heat into electricity. Halotechnics is developing a scalable system to pump, heat, store, and discharge the molten glass. The company is leveraging technology used in the modern glass industry, which has decades of experience handling molten glass.

Harvard University

Small Organic Molecule Based Flow Battery

Harvard University is developing an innovative grid-scale flow battery to store electricity from renewable sources. Flow batteries store energy in external tanks instead of within the battery container, permitting larger amounts of stored energy at lower cost per kWh. Harvard is designing active material for a flow battery that uses small, inexpensive organic molecules in aqueous electrolyte. Relying on low-cost organic materials, Harvard's innovative storage device concept would yield one or more systems that may be developed by their partner, Sustainable Innovations, LLC, into viable grid-scale electrical energy storage systems.

Iowa State University

Development and Testing of New Low Cost, Safe, and Efficient All Solid State Sodium Batteries for GRID scale energy Storage and Other Applications

The team led by Iowa State University (ISU) will develop an All Solid-State Sodium Battery (ASSSB) that will have a high energy content, can easily be recycled, and rely on highly abundant and extremely low cost starting materials. Commercially available sodium-based batteries operate at elevated temperatures, which decreases the efficiency and safety of the system. The team seeks to improve all three of the main components of a sodium-based battery: the anode, cathode, and electrolyte separator. The team's anode is a porous carbon nanotube layer that will serve as a framework on which sodium metal will be deposited. The separator will be made of a novel oxy-thio-nitride glass solid electrolyte, and the cathode will be composed of a polymer in which reversible sodium insertion and removal takes place. The team will need to overcome several challenges, including reducing interfacial resistance between the organic electrode and the solid electrolyte. The proposed sodium battery can operate at room temperature, uses a benign and scalable solid-stack design for a long cycle life, and expects to achieve an energy density eqivalent to state-of-the-art Li-ion cells.

ITN Energy Systems, Inc.

Demonstration of 2.5kW/10kWh Vanadium Redox Flow Battery (VRFB) through rationally designed high energy density electrolytes and Membrane-Electrode Assembly (MEA)

ITN Energy Systems is developing a vanadium redox flow battery for residential and small-scale commercial energy storage that would be more efficient and affordable than today's best energy storage systems. In a redox flow battery, chemical reactions occur that allow the battery to absorb or deliver electricity. Unlike conventional batteries, flow batteries use a liquid (also known as an electrolyte) to store energy; the more electrolyte that is used, the longer the battery can operate. Vanadium electrolyte-based redox flow battery systems are a technology for today's market, but they require expensive ion-exchange membranes. In the past, prices of vanadium have fluctuated, increasing the cost of the electrolyte and posing a major obstacle to more widespread adoption of vanadium redox flow batteries. ITN's design combines a low-cost ion-exchange membrane and a low-cost electrolyte solution to reduce overall system cost, ultimately making a vanadium redox flow battery cost-competitive with more traditional lead-acid batteries.

Lawrence Berkeley National Laboratory

Hydrogen-Bromine Flow Batteries for Grid-Scale Energy Storage

Lawrence Berkeley National Laboratory (LBNL) is designing a flow battery for grid storage that relies on a hydrogen-bromine chemistry which could be more efficient, last longer, and cost less than today's lead-acid batteries. Flow batteries are fundamentally different from traditional lead-acid batteries because the chemical reactants that provide their energy are stored in external tanks instead of inside the battery. A flow battery can provide more energy because all that is required to increase its storage capacity is to increase the size of the external tanks. The hydrogen-bromine reactants used by LBNL in its flow battery are inexpensive, long lasting, and provide power quickly. The cost of the design could be well below $100 per kilowatt hour, which would rival conventional grid-scale battery technologies.

Massachusetts Institute of Technology

Advanced Thermo-Adsorptive Battery Climate Control System (ATB)

Massachusetts Institute of Technology (MIT) is developing a low-cost, compact, high-capacity, advanced thermo-adsorptive battery (ATB) for effective climate control of EVs. The ATB provides both heating and cooling by taking advantage of the materials' ability to adsorb a significant amount of water. This efficient battery system design could offer up as much as a 30% increase in driving range compared to current EV climate control technology. The ATB provides high-capacity thermal storage with little-to-no electrical power consumption. MIT is also looking to explore the possibility of shifting peak electricity loads for cooling and heating in a variety of other applications, including commercial and residential buildings, data centers, and telecom facilities.

Massachusetts Institute of Technology

Metallic composites phase-change materials for high-temperature thermal energy storage

Massachusetts Institute of Technology (MIT) is developing efficient heat storage materials for use in solar and nuclear power plants. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night--when the sun's not out--to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. MIT is designing nanostructured heat storage materials that can store a large amount of heat per unit mass and volume. To do this, MIT is using phase-change materials, which absorb a large amount of latent heat to melt from solid to liquid. MIT's heat storage materials are designed to melt at high temperatures and conduct heat well--this makes them efficient at storing and releasing heat and enhances the overall efficiency of the thermal storage and energy-generation process. MIT's low-cost heat storage materials also have a long life cycle, which further enhances their efficiency.

Massachusetts Institute of Technology

Electroville: High-Amperage Energy Storage Device-Energy Storage for the Neighborhood

Led by Massachusetts Institute of Technology (MIT) professor Donald Sadoway, the Electroville project team is creating a community-scale electricity storage device using new materials and a battery design inspired by the aluminum production process known as smelting. A conventional battery includes a liquid electrolyte and a solid separator between its 2 solid electrodes. MIT's battery contains liquid metal electrodes and a molten salt electrolyte. Because metals and salt don't mix, these 3 liquids of different densities naturally separate into layers, eliminating the need for a solid separator. This efficient design significantly reduces packaging materials, which reduces cost and allows more space for storing energy than conventional batteries offer. MIT's battery also uses cheap, earth-abundant, domestically available materials and is more scalable. By using all liquids, the design can also easily be resized according to the changing needs of local communities.


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