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Lithium Electrode Sub-Assemblies

24M Technologies

Large-Area Lithium Electrode Sub-Assemblies (LESAs) Protected by Self-Forming Microstructured Polymer-Inorganic Single-Ion Conducting Composites

Program: 
ARPA-E Award: 
$3,484,674
Location: 
Cambridge, MA
Project Term: 
01/03/2017 to 01/02/2020
Project Status: 
ACTIVE
Technical Categories: 
Critical Need: 

Demand for Lithium-ion (Li-ion) batteries has increased significantly as products such as smartphones, laptops, electric vehicles, and grid storage batteries rise in popularity. However, Li-ion batteries have numerous safety and performance limitations due to their flammable electrolyte and the charge storage density of their active materials, which are not easily overcome by incremental progress. New types of high-performance separators and electrodes built with solid-state ion conductors could simultaneously improve the energy density and safety of lithium ion batteries by removing the most flammable battery components, and also improving the driving range and durability of electric vehicles. Solid-state separators also open the door to the use of lithium metal as an active material, resulting in a significant increase in cell energy content, and the subject of research efforts for the past several decades. New battery technology that employs energy dense, thermally stable, and long-lasting materials will also be of interest for grid storage, particularly in dense, urban environments where the space occupied by storage systems is more of a concern.

Project Innovation + Advantages: 

24M Technologies will lead a team to develop low cost, durable, enhanced separators/solid state electrolytes to build batteries using a lithium metal anode. Using a polymer/solid electrolyte ceramic blend, 24M will be able to make a protective layer that will help eliminate side reactions that have previously contributed to performance degradation and provide a robust mechanical barrier to branchlike metal fibers called dendrites. Unimpeded, dendrites can grow to span the space between the negative and positive electrodes, causing a short-circuit. The resulting, large-area lithium electrode sub-assemblies, or LESAs, will be cost-effective solutions that are scalable to high-volume manufacturing while providing a toolbox to further tailor electrode performance.

Potential Impact: 

If successful, developments made under the IONICS program will increase the energy storage content for vehicle batteries by about 30% compared to today's Li-ion batteries and significantly reduce battery storage system costs.

Security: 

IONICS program innovations could contribute to energy storage solutions for transportation and the grid, lessening U.S. dependence on imported oil and improving grid resilience.

Environment: 

A 10% increase in electric vehicle use would reduce US oil consumption by 3% and reduce total US CO2 emissions by 1%.

Economy: 

IONICS program innovations could further establish U.S. businesses as technical leaders in energy storage, encouraging greater use of readily available renewable resources and increasing the competitiveness of electric vehicles.

Contacts
ARPA-E Program Director: 
Dr. Paul Albertus
Project Contact: 
Elizabeth DiCocco
Partners
Carnegie Mellon University
Lawrence Berkeley National Laboratory
Sepion Technologies
Release Date: 
9/13/2016