Renewable Energy to Fuels Through Utilization of Energy-Dense Liquids
Program Description:
Innovation Need:
Carbon-neutral liquid fuels as defined by REFUEL are hydrogen-rich and made by converting molecules in the air (nitrogen or carbon dioxide) and hydrogen from water into an energy-carrying liquid using renewable power. While existing fuel-cell electric vehicles (FCEVs) use pure hydrogen as a fuel, the limitations of hydrogen storage and transportation have made it difficult and expensive to build transmission, distribution, and refueling infrastructure for mass adoption of these vehicles. The CNLFs of REFUEL address these challenges by using the infrastructure already in use by traditional liquid fuels. Once the CNLF arrives at its point of use, it can be used to generate electricity in a fuel cell or produce hydrogen on demand, greatly reducing transportation and storage costs.
REFUEL projects will aid in the development of energy sources that are readily produced and easily transported, like ammonia. REFUEL program and related projects have developed promising component technologies and small systems for the synthesis and use of ammonia at scale of up to 10 kg/day. Developments include new catalysts, reactor designs, separation strategies, strategies for accommodating intermittent electrical power, and technologies to convert ammonia to hydrogen or electricity. These technologies, however, still face significant technical risk. They are small-scale, and typically focused on one piece of the overall process of ammonia synthesis and use.
ARPA-E will also support an additional project team to integrate technology components and validate technology performance using renewable energy sources under realistic conditions at a field test site. To mitigate the substantial negative energy and environmental consequences associated with the current chemical process to synthesize ammonia, ARPA-E is funding a pre-production, integrated system involving a skid-mounted ammonia synthesis system at a production scale of 1 metric ton of ammonia per day and validating some ammonia use technologies at smaller scale.
Potential Impact:
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Project Listing
• Chemtronergy - Cost-effective, Intermediate-temperature Fuel Cell for Carbon-free Power Generation
• Chemtronergy - Solid Oxide Fuel Cell System
• FuelCell Energy - Protonic Ceramics for Ammonia
• Gas Technology Institute (GTI) - Dimethyl Ether Synthesis from Renewables
• Giner - Anion Exchange Membrane Ammonia Production
• Molecule Works - Electrochemical Membrane Reactor for Ammonia
• Opus 12 - Carbon Dioxide Conversion to Ethanol
• Rensselaer Polytechnic Institute (RPI) - H2 From Thermal Catalytic Ammonia Decomposition
• Research Triangle Institute (RTI) - Renewables-Based Catalytic Ammonia Production
• RTI International - Next-Generation Ammonia System Integration Utilizing Intermittent Renewable Power
• SAFCell - Electrochemical Ammonia Conversion
• Skyre - Carbon Dioxide to Dimethyl Ether
• Storagenergy Technologies - Solid-State Alkaline Electrolyzer Ammonia Synthesis
• University of Delaware (UD) - Direct Ammonia Fuel Cells
• University of Minnesota (UMN) - Wind Energy to Ammonia Synthesis
• West Virginia University Research Corporation (WVURC) - Microwave-Plasma Ammonia Synthesis
• Wichita State University - Alkaline Membrane-Based Ammonia Electrosynthesis