Transportation Fuels

Rice University will develop a first of its kind biocatalyst to synthesize ammonia from small–scale isolated methane sources. The microorganisms will be engineered to maximize simultaneous diazotrophic and methanotrophic capabilities. Diazotrophs are organisms that can fix nitrogen gas in the air into a biologically usable form, such as ammonia. Methanotrophs are organisms that metabolize and use methane as an energy and carbon source. Rice University’s technology will combine these capabilities, and develop a one-step ammonia synthesis that will operate at low temperature and pressure.

The Colorado School of Mines will develop a membrane reactor concept to synthesize ammonia at ambient pressure. In traditional ammonia production processes, nitrogen (N2) and hydrogen (H2) compete for identical catalyst sites, and the presence of each inhibits the other, with the overall rate reflecting a compromise. The team proposes decoupling and independently controlling the N2 and H2 dissociation by dedicating one side of the composite membrane to each. In this way, the catalysts may be individually optimized.

Space Orbital Services, in conjunction with SRI International, proposes to conduct laboratory-based, small-scale research to develop a methane conversion technology that employs unconventional chemistry at relatively low temperature, based on impacting a common alloy catalyst. The project uses laboratory experiments to establish, measure and refine operational parameters including conversion rates and efficiency, reaction products, and reactor design.

The University of Florida is developing a windowless high-temperature chemical reactor that converts concentrated solar thermal energy to syngas, which can be used to produce gasoline. The overarching project goal is lowering the cost of the solar thermochemical production of syngas for clean and synthetic hydrocarbon fuels like petroleum. The team will develop processes that rely on water and recycled CO2 as the sole feed-stock, and concentrated solar radiation as the sole energy source, to power the reactor to produce fuel efficiently.

The University of Minnesota (UMN) is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. UMN envisions producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration.

MIT is developing a thermal energy storage device that captures energy from the sun; this energy can be stored and released at a later time when it is needed most. Within the device, the absorption of sunlight causes the solar thermal fuel's photoactive molecules to change shape, which allows energy to be stored within their chemical bonds. A trigger is applied to release the stored energy as heat, where it can be converted into electricity or used directly as heat. The molecules would then revert to their original shape, and can be recharged using sunlight to begin the process anew.

Lawrence Berkeley National Laboratory (LBNL) is improving the natural ability of a common soil bacteria called Ralstonia eutropha to use hydrogen and carbon dioxide for biofuel production. First, LBNL is genetically modifying the bacteria to produce biofuel at higher concentrations. Then, LBNL is using renewable electricity obtained from solar, wind, or wave power to produce high amounts of hydrogen in the presence of the bacteria—increasing the organism's access to its energy source and improving the efficiency of the biofuel-creation process.

Medical University of South Carolina (MUSC) is developing an engineered system to create liquid fuels from communities of interdependent microorganisms. MUSC is first pumping carbon dioxide (CO2) and renewable sources of electricity into a battery-like cell. A community of microorganisms uses the electricity to convert the CO2 into hydrogen. That hydrogen is then consumed by another community of microorganisms living in the same system. These new microorganisms convert the hydrogen into acetate, which in turn feed yet another community of microorganisms.

The University of Massachusetts at Amherst (UMass Amherst) is feeding renewable electricity to bacteria to provide the microorganisms with the energy they need to turn carbon dioxide (CO2) directly into liquid fuels. UMass Amherst's energy-to-fuels conversion process is anticipated to be more efficient than current biofuels approaches in part because this process will leverage the high efficiency of photovoltaics to convert solar energy into electricity.

North Carolina State University (NC State) is working with the University of Georgia to create electrofuels from primitive organisms called extremophiles that evolved before photosynthetic organisms and live in extreme, hot water environments with temperatures ranging from 167-212 degrees Fahrenheit. The team is genetically engineering these microorganisms so they can use hydrogen to turn carbon dioxide directly into alcohol-based fuels.